Enantioselective Evans-Tishchenko reduction of β-hydroxyketone catalyzed by lithium binaphtholate.
نویسندگان
چکیده
Lithium diphenylbinaphtholate catalyzed the enantioselective Evans-Tishchenko reduction of achiral β-hydroxyketones to afford monoacyl-protected 1,3-diols with high stereoselectivities. In the reaction of racemic β-hydroxyketones, kinetic optical resolution occurred in a highly stereoselective manner.
منابع مشابه
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ورودعنوان ژورنال:
- Molecules
دوره 16 6 شماره
صفحات -
تاریخ انتشار 2011